Author/Authors :
Habibi-Khorassani ، Sayyed Mostafa نويسنده , , Maghsoodlou، Malek Taher نويسنده , , Shahraki، Mehdi Hashemi نويسنده Power & Water University (Shahid Abbaspour) , , Poorshamsoddin، Mohammad Ali نويسنده Department of Chemistry, University of Sistan and Baluchestan, P. O. Box 98135-674, Zahedan, Iran , , Karimi، Mahsa نويسنده Department of Chemistry, University of Sistan and Baluchestan, P. O. Box 98135-674, Zahedan, Iran , , Abbasi، Maliheh نويسنده Department of Chemistry, University of Sistan and Baluchestan, P. O. Box 98135-674, Zahedan, Iran ,
Abstract :
Sucrose is applied as an efficient catalyst for the three-component reaction consisting of aromatic aldehydes, malononitrile and resorcinol in a mixture of water and ethanol media as green solvents. The advantages of this method are excellent yeild, inexpensive catalyst and more environmentally friendly. Mechanistic insight into the synthesis of 2-amino-4H-chromene included spectral kinetics approaches is revealed. From the temperature, concentration and solvent studies, the activation energy (Ea=102 kJmol-1) and the related kinetic parameters (?G?=41 kJmol-1, ?S?=195 Jmol-1 and ?H?=99 kJ mol-1) are calculated. The first step of proposed mechanism is recognized as a rate-determining step (k1) and this is confirmed based upon the steady-state approximation.
