Sonochemical and thermal redox reactions of triphenylmethane and triphenylmethyl carbinol in nitrobenzene

The reaction of triphenylmethane and triphenylcarbinol with nitrobenzene under thermal or ultrasonic activation was studied. It was shown beyond doubt that the thermal reaction of the aforementioned systems at 210°C occurs through electron transfer. The sonochemical reactions occur at 40°C, although slowly, while heating at the same temperature leaves the system unchanged. Electron transfers are also involved but an unexpected reductive process was evident.