Title of article :
Excess molar enthalpies and excess molar volumes of methyl methacrylate + benzene, + toluene, + p-xylene, + cyclohexane and + aliphatic diethers (diethyl, diisopropyl and dibutyl)
Author/Authors :
George، نويسنده , , John and Sastry، نويسنده , , N.V and Prasad، نويسنده , , D.H.L، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Pages :
13
From page :
39
To page :
51
Abstract :
Experimental values of excess molar enthalpies (HmE) at T=298.15 K and excess molar volumes (VmE) at T=298.15–318.15 K for binary liquid mixtures of methyl methacrylate (MMA) + benzene, + toluene, + p-xylene, + cyclohexane and + diethers (diethyl, diisopropyl and dibutyl) are reported. The qualitative analysis of both the excess molar functions was done taking in to consideration the molecular size of ethers and the nature of the hydrocarbon. The results show that besides the weakening of dipolar forces among ester molecules, specific but weak interactions of n⋯π and dipole–dipole types are significant in these mixtures (with an exception in MMA+cyclohexane).
Keywords :
Density , Enthalpy , Ethers + hydrocarbon mixtures , excess molar volume
Journal title :
Fluid Phase Equilibria
Serial Year :
2003
Journal title :
Fluid Phase Equilibria
Record number :
2033758
Link To Document :
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