Author/Authors :
Nakatsuji، نويسنده , , S. and Satoki، نويسنده , , S. and Suzuki، نويسنده , , K. and Enoki، نويسنده , , T. and Kinoshita، نويسنده , , N. and Anzai، نويسنده , , H.، نويسنده ,
Abstract :
The reaction of lithio derivative of TTF with 4-oxo-TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) in diethylether gave hydroxy-TEMPO-substituted TTF derivative 1. Phenoxyl-substituted TTF derivative 2 was prepared from the lithio derivative of TTF with 2,6-di-t-butyl-p-benzoquinone via phenol intermediate. Each donors had moderate oxidation potentials estimated from CV measurement and gave CT complexes with several acceptors as I2, DDQ or TCNQF4.
