Title of article
Structural and electrical properties of BETS compounds with transition metal complex anions
Author/Authors
Kobayashi، نويسنده , , H. and Arai، نويسنده , , E. I. Sato، نويسنده , , A. and Naito، نويسنده , , T. and Tanaka، نويسنده , , H. and Kobayashi، نويسنده , , A. and Saito، نويسنده , , T. and Cassoux، نويسنده , , P.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1997
Pages
2
From page
1595
To page
1596
Abstract
BETS (=bis(ethylenedithio)tetraselenafulvalene) conductors with M(CN)4 anions (M=Pd, Pt) are metallic down to 4K. Crystals of MCl4 salts (M=Co, Ni, In) are metallic down to 4 K. BETS2InCl5[(C2H5)4N]0.7 undergoes a gradual metal-insulator transition around 50 K. The magnetic susceptibility of BETS4CU2Cl6 exhibits a round maximum showing an antiferromagnetic interaction between Cu2+ in Cu2Cl62− anions (J=163 K). The electrical properties and crystal structures of BETS complexes with M(dts)2 (M=Au, Pd, Pt; dts= dithiosquarate) are briefly mentioned.
Keywords
Organic conductors based on radical cation and/or anion salts , Metal-insulator phase transitions
Journal title
Synthetic Metals
Serial Year
1997
Journal title
Synthetic Metals
Record number
2071079
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