Title of article
Structural and physical properties of molecular metals based on BEDO-TTF
Author/Authors
Horiuchi، نويسنده , , Sachio and Yamochi، نويسنده , , Hideki and Saito، نويسنده , , Gunzi and Matsumoto، نويسنده , , Kiyoshi، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1997
Pages
2
From page
1809
To page
1810
Abstract
Preparation, characterization, and physical properties of several metallic bis(ethylenedioxy)tetrathiafulvalene (BEDO-TTF) complexes are presented. The direct reaction with chloranilic acid (H2CHA) gave 2:1 complex, the crystal structure of which consists of two-dimensional (2D) donor layer and 1D stack of deprotonated acceptor molecules. The electrocrystallization of the donor in the presence of MnBr42− and water yielded a novel salt with four components, (BEDO-TTF)2Br[MnBr2(H2O)4](H2O), which contains 2D donor layers and localized magnetic moments (S = 52).
Keywords
Electrocrystallization , Conductivity , X-ray diffraction , Magnetic measurements
Journal title
Synthetic Metals
Serial Year
1997
Journal title
Synthetic Metals
Record number
2071160
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