• Title of article

    Synthesis and redox properties of TCNQ and DCNQI-type electron-acceptor methanofullerenes

  • Author/Authors

    Martيn، نويسنده , , Nazario and Knight، نويسنده , , Brian and Wudl، نويسنده , , Fred، نويسنده ,

  • Issue Information
    دوماهنامه با شماره پیاپی سال 1997
  • Pages
    4
  • From page
    2271
  • To page
    2274
  • Abstract
    The first TCNQ- and DCNQI-type spiromethanofullerenes (4 and 5) have been prepared from the quinone-type spiromethanofullerene 3 by reaction with the Lehnert reagent (malonitrile, titanium tetrachloride and pyridine) and bis(trimethylsilyl)carbodiimide (BTC) and titanium tetrachloride, respectively. The cyclic voltammetry reveals that these novel compounds are better acceptors than the starting quinone-type spiromethanofullerene and comparable to the parent [60]fullerene.
  • Keywords
    Fullerenes and derivatives , Electrochemical methods
  • Journal title
    Synthetic Metals
  • Serial Year
    1997
  • Journal title
    Synthetic Metals
  • Record number

    2071374