Microtubes of conducting polymers

A new simple method termed as in-situ doping polymerization at presence of special organic sulfonic acids as dopants was proposal to synthesize conducting microtubes of polypyrrole (PPy) and polyaniline (PANI), The resulting microtubes not only show high conductivity at room temperature (e.g 27 S/cm for PPy and 4 S/cm for PANI), but also are soluble in some organic solvents. Compared to “template synthesisi± method, which is an effective method to synthesize microtubes of conducting polymers, the new method proposed by authors is much simpler without using template membrane and “molecular anchor”, which are required for “template synthesis” method.