Title of article
Synthesis and properties of new PDT- and TPDT-TTP analogues
Author/Authors
Kaibuki، نويسنده , , T. and Misaki، نويسنده , , Y. and Tanaka، نويسنده , , K. and Takimiya، نويسنده , , K. and Morikami، نويسنده , , A. and Otsubo، نويسنده , , T.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1999
Pages
2
From page
1621
To page
1622
Abstract
2-(1,3-Diselenol-2-ylidene)-5-(pyran-4-ylidene)-1,3,4,6-tetrathiapentalene (PDS-TTP), its thiopyran analogue (TPDS-TTP), and their bis(methylthio) derivatives have been prepared. Their first and second oxidation potentials are comparable to those of the corresponding sulfur analogues. The PF6 and AsF6 salt of PDS-TTP displayed metallic conductivity down to 4.2 K, and TCNQ complex was semiconductor with a low activation energy (0.006 eV).
Keywords
Electrocrystalization , Electrochemical methods , Organic conductors based on radical cation , anion salts
Journal title
Synthetic Metals
Serial Year
1999
Journal title
Synthetic Metals
Record number
2072784
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