Title of article
Novel sulfonate containing ET based synmetals
Author/Authors
Hau Wang، نويسنده , , H. and Geiser، نويسنده , , Urs and Schlueter، نويسنده , , John A. and Ward، نويسنده , , Brian H. and Parakka، نويسنده , , James P. and Kini، نويسنده , , Aravinda M. and OʹMalley، نويسنده , , Jennifer L. and Thomas، نويسنده , , Seddon Y. and Morales، نويسنده , , Emilio and Dudek، نويسنده , , James D. and Williams، نويسنده , , Jack M. and gard، نويسنده , , Gary L.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1999
Pages
4
From page
1666
To page
1669
Abstract
Electrocrystallization of ET in the presence of aromatic and aliphatic sulfonate anions has led to many new ET salts. These new ET based sulfonate complexes are characterized with use of x-ray diffraction, four-probe conductivity measurements, ESR and Raman spectroscopies. A new κ(4 × 4) donor packing motif was observed in (ET)2(C6H5CH2SO3)(H2O). Strong hydrogen bonding between the sulfonate anion S-O and the donor ethylene C-H provides the driving force for the ET salt formation. Many of these new sulfonate salts are highly conductive with some remaining metallic to ~ 4 K.
Keywords
Electrocrystallization , BEDT-TTF , X-ray diffraction , ESR , Transport measurement , Raman spectroscopy
Journal title
Synthetic Metals
Serial Year
1999
Journal title
Synthetic Metals
Record number
2072801
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