Author/Authors :
Nishikawa، نويسنده , , H. and Sato، نويسنده , , T. and Kodama، نويسنده , , T. and Ikemoto، نويسنده , , Alexander I. and Kikuchi، نويسنده , , K. and Anzai، نويسنده , , H. and Yamada، نويسنده , , J.، نويسنده ,
Abstract :
The selenium containing TTF donors condensed with a 1,4-dioxane or a 1,4-dithiane ring by cis fusion were synthesized as organic donors with a bulky substituent. X-ray diffractional analysis of 1c (DOES) revealed that the conformation at the 1,4-dioxane ring fusion site is cis similar to the case of DOET. Several cation-radical salts based on 1b and 1c exhibited metallic conducting behavior.
Keywords :
DOET derivatives , bulky substituent , crystal structure , Metal , Electrocrystallization
