Author/Authors :
Bérézovsky، نويسنده , , F. and Triki، نويسنده , , S. and Sala Pala، نويسنده , , J. and Galلn-Mascarَs، نويسنده , , J.R. and Gَmez-Garcيa، نويسنده , , C.J. and Coronado، نويسنده , , E.، نويسنده ,
Abstract :
A new radical cation salt formulated as (ET)5.5[Cr(NCS)6] (ET = BEDT-TTF = bis(ethylene)dithiotetrathiafulvalene) has been synthesised and characterised by X-ray diffraction and magnetic measurements. The structure shows the presence of alternating layers of the ET units and mixed layers of anions and an isolated ET molecule. The magnetic susceptibility data in the temperature range 2–300 K show a Curie law with C = 1.771 cm3.K.mol−1 and Nα = 1.20.10−5 cm3.mol−1, in agreement with the presence of isolated Cr(III) without any contribution from the organic part.
