• Title of article

    Radical cation salts based on BEDT-TTF and the paramagnetic anion [Cr(NCS)6]3−

  • Author/Authors

    Bérézovsky، نويسنده , , F. and Triki، نويسنده , , S. and Sala Pala، نويسنده , , J. and Galلn-Mascarَs، نويسنده , , J.R. and Gَmez-Garcيa، نويسنده , , C.J. and Coronado، نويسنده , , E.، نويسنده ,

  • Issue Information
    دوماهنامه با شماره پیاپی سال 1999
  • Pages
    2
  • From page
    1755
  • To page
    1756
  • Abstract
    A new radical cation salt formulated as (ET)5.5[Cr(NCS)6] (ET = BEDT-TTF = bis(ethylene)dithiotetrathiafulvalene) has been synthesised and characterised by X-ray diffraction and magnetic measurements. The structure shows the presence of alternating layers of the ET units and mixed layers of anions and an isolated ET molecule. The magnetic susceptibility data in the temperature range 2–300 K show a Curie law with C = 1.771 cm3.K.mol−1 and Nα = 1.20.10−5 cm3.mol−1, in agreement with the presence of isolated Cr(III) without any contribution from the organic part.
  • Keywords
    Electrocrystallization , Magnetic measurements
  • Journal title
    Synthetic Metals
  • Serial Year
    1999
  • Journal title
    Synthetic Metals
  • Record number

    2072851

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2072851