Title of article :
Pressure-induced insulating state in (BO)2Cl(H2O)x
Author/Authors :
Hanazato، نويسنده , , S. and Mori، نويسنده , , T. and Mori، نويسنده , , H. and Tanaka، نويسنده , , S.، نويسنده ,
Issue Information :
دوماهنامه با شماره پیاپی سال 1999
Abstract :
The title compound is a θ-phase salt which exhibits metallic conductivity down to low temperatures. Since the universal phase diagram of θ-phase predicts the existence of an insulating phase under pressure, conductivity under high pressure has been investigated. The metallic temperature dependence is switched to flat dependence above 4 kbar, and semiconducting dependence appears above 10 kbar.
Keywords :
Metal-insulator phase transitions , Organic conductors based on radical cation and/or anion salts , X-ray absorption spectroscopy
Journal title :
Synthetic Metals
Journal title :
Synthetic Metals
