• Title of article

    Metal-insulator transition in (TTM-TTP)(I3)5/3 with high oxidation state

  • Author/Authors

    Kawamoto، نويسنده , , T. and Mori، نويسنده , , T. and Misaki، نويسنده , , Y. and Tanaka، نويسنده , , K. and Mori، نويسنده , , H. and Tanaka، نويسنده , , S.، نويسنده ,

  • Issue Information
    دوماهنامه با شماره پیاپی سال 1999
  • Pages
    2
  • From page
    1829
  • To page
    1830
  • Abstract
    (TTM-TTP)(I3)5/3 (TTM-TTP: 2,5-bis[4,5-(methylthio)-1,3-dithiol-2-ylidene]-1,3,4,6-tetrathiapentalene) and its isostructual methylseleno-substituted compounds show metallic behavior above tmi ≈ 20 K in spite of large positive charge +5/3. High pressure resistivity and ESR measurements have been carried out. Both salts remain paramagnetic down to 2.9 K; no evidence of spin-Peierls or antiferromagnetic transition is obtained.
  • Keywords
    electron spin resonance , Organic conductors based on radical cation salts , Metal-insulator phase transitions , Conductivity
  • Journal title
    Synthetic Metals
  • Serial Year
    1999
  • Journal title
    Synthetic Metals
  • Record number

    2072891