Title of article
C60complexes with dianthracene and triptycene: synthesis and crystal structures
Author/Authors
Konarev، نويسنده , , D.V. and Zubavichus، نويسنده , , Y.V. and Valeev، نويسنده , , E.F. and Slovokhotov، نويسنده , , Yu.L. and Shulʹg، نويسنده , , Yu.M. and Lyubovskay، نويسنده , , R.N.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 1999
Pages
2
From page
2364
To page
2365
Abstract
New molecular complexes of fullerene C60 with aromatic hydrocarbons TPC·C60 and DAN·C60(C6H6)3, were obtained. For the first time a three-dimensional packing of fullerene molecules is observed in TPC·C60. The DAN·C60(C6H6)3 complex has a layered structure with alternating sheets of C60 and donor molecules. Complexes with strong van der Waals interaction were formed due to the shape concordance between the TPC, DAN and spherical C60 molecules. XPS spectroscopy of the complexes showed the suppression of π-π* transitions in TPC and DAN phenyl rings in the complexes due to the donor- C60 interaction.
Keywords
single crystal growth , X-ray diffraction , XPS-spectroscopy , Fullerenes
Journal title
Synthetic Metals
Serial Year
1999
Journal title
Synthetic Metals
Record number
2073145
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