Femtosecond photo-current excitation cross-correlation on a ladder type polymer

Transient photo-current cross-correlation experiments were carried out on methyl substituted ladder type poly(para-phenylene) (m-LPPP). In this experiment, the first pulse at 390 nm creates singlet excitons (S0→S1), that are re-exited to a higher lying state by the time delayed second pulse at 780 nm (S1→Sn). The change in (390 nm)-induced photo-current caused by the 780 nm pulses is measured as a function of blue–red time delay. Our measurements show that the charge generation rate is highly increased if the exciton is re-excited within the first picosecond, pointing out the role of exciton migration in the ionization process. For longer time delays, we see a charge generation rate, that follows the excited state population, suggesting enhanced dissociation from a higher lying state.