Title of article
Molecular conductors based on radical cation hydrated halides: new crystal phase of the (BEDT-TTF)3Br2·2H2O organic metal
Author/Authors
Khasanov، نويسنده , , S.S. and Zorina، نويسنده , , L.V. and Shibaeva، نويسنده , , R.P. and Pesotskii، نويسنده , , S.I. and Kartsovnik، نويسنده , , M.V. and Veiros، نويسنده , , L.F. and Canadell، نويسنده , , E.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 2002
Pages
8
From page
41
To page
48
Abstract
A new crystal phase of the (BEDT-TTF)3Br2·2H2O radical cation salt was characterized by single crystal X-ray diffraction, electrical resistivity measurements at ambient and high pressures and electronic band structure calculations. (BEDT-TTF)3Br2·2H2O is triclinic with space group P1 (a=11.225(2) Å, b=13.964(3) Å, c=16.141(3) Å, α=94.48(3)°, β=109.01(3)°, γ=97.08(3)°, V=2354.8(8) Å3, Z=2). The salt is similar to the corresponding chloride salt in its donor molecular packing motif and electronic structure but differs in its transport properties.
Keywords
molecular conductors , Transport properties , Crystal and electronic structures
Journal title
Synthetic Metals
Serial Year
2002
Journal title
Synthetic Metals
Record number
2076800
Link To Document