Title of article :
Physical properties and crystal structures of BDA-TTP conductors
Author/Authors :
Yamada، نويسنده , , J. and Watanabe، نويسنده , , M. and Toita، نويسنده , , T. and Akutsu، نويسنده , , H. and Nakatsuji، نويسنده , , S. and Nishikawa، نويسنده , , H. and Ikemoto، نويسنده , , Alexander I. and Kikuchi، نويسنده , , K.، نويسنده ,
Issue Information :
دوماهنامه با شماره پیاپی سال 2003
Abstract :
The preparation of charge-transfer (CT) salts composed of a new non-TTF donor 2,5-bis(1,3-dithian-2-ylidene)-1,3,4,6-tetrathiapentalene (BDA-TTP) has been investigated to develop new molecular-based organic superconductors and magnetic conductors. The BDA-TTP donor produces the superconducting β-(BDA-TTP)2X (X=SbF6, AsF6, and PF6) salts, and β-(BDA-TTP)2FeCl4 exhibits metallic conducting behavior with a metal-to-insulator (MI) transition at 113 K, as well as antiferromagnetism below the Néel temperature of near 8.5 K.
Keywords :
Organic superconductors , Organic conductors based on radical cation salts , Electrocrystallization , Conductivity , Magnetic measurements
Journal title :
Synthetic Metals
Journal title :
Synthetic Metals
