Author/Authors :
Yamamoto، نويسنده , , T. and Tajima، نويسنده , , H. and Kato، نويسنده , , R. and Uruichi، نويسنده , , M. and Yakushi، نويسنده , , K.، نويسنده ,
Abstract :
We measured thermoelectric power and Raman spectra for (Me2DCNQI)2CuxLi1−x. The ν8 (quinoid CN stretch) Raman line shifts downwards with an increase of copper contents (x), and exhibits a split for x≤0.24. Temperature dependence of the thermoelectric power exhibits drastic change between x=0.14 and x=0.22. This behaviour is consistent with the phase diagram previously determined.
Keywords :
Metal–insulator transition , Raman spectra , DCNQI salt , thermoelectric power