Title of article
Design of quantum neutral–ionic phase transition in organic charge-transfer complexes
Author/Authors
Horiuchi، نويسنده , , S. and Kumai، نويسنده , , R. and Okimoto، نويسنده , , Y. and Tokura، نويسنده , , Y.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 2003
Pages
4
From page
615
To page
618
Abstract
Neutral–ionic (NI) phase transition has been investigated by various chemical modifications in the prototype complexes of TTF (or DMTTF)-p-chloranil. Successive lattice expansion due to the enlarged molecular size serves to lower the NI transition temperature. From the dielectric properties and the molecular ionicity, we demonstrate the novel examples of the NI transition, which is affected by the quantum fluctuation effect.
Keywords
dielectric properties , Charge-transfer complex , phase diagram , Quantum paraelectricity , Neutral–ionic phase transition
Journal title
Synthetic Metals
Serial Year
2003
Journal title
Synthetic Metals
Record number
2077359
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