Title of article
Post-functionalization of poly(3-hexylthiophene) via anodic chlorination
Author/Authors
Hayashi، نويسنده , , Shotaro and Inagi، نويسنده , , Shinsuke and Hosaka، نويسنده , , Kenta and Fuchigami، نويسنده , , Toshio، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 2009
Pages
4
From page
1792
To page
1795
Abstract
Selective anodic chlorination of a poly(3-hexylthiophene) was successfully carried out by electrochemical polymer reaction. NMR and EDX analyses revealed the selective and sufficient substitution of chlorine atom at the 4-position of the repeating thiophene ring. GPC measurement of the polymer before and after electrolysis indicated that neither decomposition nor propagation of the polymer occurred even after passage of the excess charge. The optical and electrochemical properties of the obtained chlorinated polymer were investigated in detail.
Keywords
Electrochemical polymer reaction , Anodic chlorination , solid-phase synthesis , Polythiophene
Journal title
Synthetic Metals
Serial Year
2009
Journal title
Synthetic Metals
Record number
2085671
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