Title of article
Acylation and oxidation of primary amines and alcohols catalyzed by nanoporous polyaniline emeraldine salt
Author/Authors
Lee، نويسنده , , Chan Woo and Hwang، نويسنده , , Ho Yun and Jeong، نويسنده , , Han Mo and Yoon، نويسنده , , Ung Chan and Chi، نويسنده , , Ki-Whan، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 2009
Pages
4
From page
1820
To page
1823
Abstract
We described the convenient and efficient catalytic acylation and oxidation of primary amines and alcohols compounds into amide/ester or aldehyde compounds using nanoporous polyaniline emeraldine salts catalysts. The reaction mechanism of acylation by polyaniline emeraldine salt catalyst is explained by acid catalyzed addition–elimination reaction, whereas oxidation process is proposed to occur through a radical pathway.
Keywords
Amine , Polyaniline catalyst , Emeraldine salt , acylation , Oxidation , alcohol
Journal title
Synthetic Metals
Serial Year
2009
Journal title
Synthetic Metals
Record number
2085685
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