• Title of article

    A photoluminiscent Ge-containing conjugated macrocycle

  • Author/Authors

    Sengupta، نويسنده , , Arijit and Ghosh، نويسنده , , Sutapa and Peetz، نويسنده , , Ralf M.، نويسنده ,

  • Issue Information
    دوماهنامه با شماره پیاپی سال 2010
  • Pages
    4
  • From page
    2037
  • To page
    2040
  • Abstract
    The selective synthesis of a photoluminiscent macrocycle containing germanium atoms in conjugation with two aromatic segments has been accomplished by ruthenium-based olefin metathesis. The macrocycle shows blue emission with 40% quantum efficiency. The optical properties are interpreted with the help of theoretical DFT calculations using B3LYP/6-31G** and B3LYP/Lanl2dz with a remarkable match between the measured and the calculated absorption characteristics.
  • Keywords
    Olefin metathesis , Germanium , Blue emission , Heteroatom conjugation , macrocycle
  • Journal title
    Synthetic Metals
  • Serial Year
    2010
  • Journal title
    Synthetic Metals
  • Record number

    2087632

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2087632