Author/Authors :
Trofimov، نويسنده , , Boris A. and Markova، نويسنده , , Marina V. and Tatarinova، نويسنده , , Inna V. and Mikhaleva، نويسنده , , Al’bina I. and Morozova، نويسنده , , Lyudmila V. and Petrova، نويسنده , , Ol’ga V. and Sobenina، نويسنده , , Lyubov’ N. and Petrushenko، نويسنده , , Konstantin B. and Vakulʹskaya، نويسنده , , Tamara I. and Khutsishvili، نويسنده , , Spartak S. and، نويسنده ,
Abstract :
I2-doped and pyrrole ring-iodinated semi-conducting oligomers of N-vinyl-3-alkyl-2-phenylpyrroles have been synthesized by free-radical polymerization of the above monomers (AIBN, 2–5 wt%, 60–80 °C) and further exposure of the oligomers obtained to I2 vapor. The parent oligomers exhibit paramagnetic and fluorescent properties and stable up to 300–370 °C.
Keywords :
N-vinyl-3-alkyl-2-phenylpyrroles , paramagnetism , Free-radical polymerization , Electoconducting oligomers , N-Vinyl-2-phenylpyrrole , fluorescence