Title of article
Synthesis and structure determination of a piperidinium Zn(HPO4)ClC5H12N
Author/Authors
Rayes، نويسنده , , A and Ben Nasr، نويسنده , , C and Rzaigui، نويسنده , , M، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
11
From page
2229
To page
2239
Abstract
This article deals with the synthesis and X-ray structure determination of a new bidimentional zincophosphate (ZnPO) with formula Zn(HPO4)ClC5H12N. This phase crystallizes in the orthorhombic space group Pbca (No. 61) with parameters: a = 8.767(2) Å; b = 24.678(7) Å; c = 9.322(2) Å; V = 2016.8(1) Å3; Z = 8. Structure of this compound is determined: R = 0.026; RW = 0.033 and characterized with IR, TGA/DSC, and NMR. The structure consists of anionic parallel [Zn(HPO4)Cl]− sheets alternating with thick slabs of organic molecules (C5H12N)+. The organic molecules are linked to the anionic sheets through hydrogen bonds.
Keywords
A. layered compound , B. Crystal growth , C. X-ray diffraction , D. Crystal structure
Journal title
Materials Research Bulletin
Serial Year
2001
Journal title
Materials Research Bulletin
Record number
2095498
Link To Document