Title of article :
New rare-earth double-layered-perovskite oxyfluorides, RbLnTiNbO6F (Ln = La, Pr, Nd)
Author/Authors :
Caruntu، نويسنده , , Gabriel and Spinu، نويسنده , , Leonard and Wiley، نويسنده , , John B، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Abstract :
New Dion–Jacobson-type double-layered oxyfluoride perovskites, RbLnTiNbO6F (Ln=La, Pr, Nd), have been synthesized. Rietveld refinement of X-ray powder diffraction data (space group P4/mmm) shows the compounds to be isostructural with RbSrNb2O6F. Curie–Weiss behavior is observed in the Pr, Nd compounds. This series further illuminates the substitutional variations, both cationic and anionic, that can be achieved within the RbLaNb2O7 structure type.
Keywords :
A. Layered compounds , A. Oxides , A. Fluorides , C. X-ray diffraction , D. Crystal structure
Journal title :
Materials Research Bulletin
Journal title :
Materials Research Bulletin