Title of article :
New palladium phosphate complexes: K2PdP2O7 and K3.5Pd2.25(P2O7)2 synthesis, single crystal structure and conductivity
Author/Authors :
A. El Maadi، نويسنده , , A and Bennazha، نويسنده , , J and Réau، نويسنده , , J.M and Boukhari، نويسنده , , A and Holt، نويسنده , , E.M، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
Two new diphosphate complexes containing potassium and palladium, K2PdP2O7 and K3.5Pd2.25(P2O7)2, have been synthesized and characterized by single crystal X-ray diffraction. K2PdP2O7 exists with layers formed of linked PdP2O7 polyhedra, between which are found the potassium ions. K3.5Pd2.25(P2O7)2 with a Pd/P2O7 ratio of 1.125:1 crystallizes with tunnels of various sizes in which are found the potassium ions. Conductivity measurements reveal the material to be conducting.
Keywords :
A. Ceramics , D. Crystal structure , D. Electrical properties , C. X-ray diffraction
Journal title :
Materials Research Bulletin
Journal title :
Materials Research Bulletin
