Title of article
Soft chemistry synthesis, structure and electrochemical characterization of iron phosphates Fe(H2PO4)3 and Fe(PO3)3
Author/Authors
Baies، نويسنده , , R. and Pralong، نويسنده , , V. and Caignaert، نويسنده , , V. and Raveau، نويسنده , , B.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
8
From page
1170
To page
1177
Abstract
The iron phosphate, Fe(H2PO4)3, was synthesized through a precipitation route by means of acidic media. As the compound is highly hygroscopic, the structure was solved ab initio by powder X-ray diffraction under nitrogen flow at room temperature and 200 °C. This phase is antiferromagnetic below 30 K. It converts into Fe(PO3)3 at 550 °C, after dehydration. Electrochemical characterizations, performed on the last compound, show irreversible decomposition into metallic iron.
Keywords
C. electrochemical measurements , A. Inorganic compounds , C. Thermograviometric analysis , C. X-ray diffraction , B. Chemical synthesis
Journal title
Materials Research Bulletin
Serial Year
2006
Journal title
Materials Research Bulletin
Record number
2097695
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