Title of article
New calixarenes for nonlinear optics: synthesis and conformation of functionalized p-nitrocalix[4]arenes
Author/Authors
Regayeg، نويسنده , , Mourad and Vocanson، نويسنده , , Francis and Duport، نويسنده , , Antony and Blondeau، نويسنده , , Beryl and Perrin، نويسنده , , Monique and Fort، نويسنده , , Alain and Lamartine، نويسنده , , Roger، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
5
From page
131
To page
135
Abstract
New functionalized p-nitrocalix[4]arenes have been synthesized. They adopt a cone conformation or the less common partial cone conformation both in solution and in the solid state. They can be used as intermediates or for second-order nonlinear optics (NLO). The structure of the 11,23-dinitro-26,28-dipropoxy-25,27-di-etoxycarbonylmethoxycalix[4]arene has been determined by X-ray crystallography. The NLO activity is consistent with the solid state and solution conformations.
Keywords
Conformation , Quadratic hyperpolarizability , Calixarenes
Journal title
Materials Science and Engineering C
Serial Year
2002
Journal title
Materials Science and Engineering C
Record number
2097862
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