Author/Authors :
Drummy، نويسنده , , Lawrence F. and Koerner، نويسنده , , Hilmar and Phillips، نويسنده , , David M. and McAuliffe، نويسنده , , Joseph C. and Kumar، نويسنده , , Manoj and Farmer، نويسنده , , B.L. and Vaia، نويسنده , , Richard A. and Naik، نويسنده , , Rajesh R.، نويسنده ,
Abstract :
Recombinant protein–inorganic nanocomposites comprised of exfoliated Na+ montmorillonite (MMT) in a recombinant protein matrix based on silk-like and elastin-like amino acid motifs (silk elastin-like protein (SELP)) were formed via a solution blending process. Charged residues along the protein backbone are shown to dominate long-range interactions, whereas the SELP repeat sequence leads to local protein/MMT compatibility. Up to a 50% increase in room temperature modulus and a comparable decrease in high temperature coefficient of thermal expansion occur for cast films containing 2–10 wt.% MMT.
Keywords :
Silk , Elastin , clay , Composites , Biomaterials