• Title of article

    Magnetisation studies of phase co-existence in Gd1 − xCaxBaCo2O5.5

  • Author/Authors

    Thirumurugan، نويسنده , , N. and Bharathi، نويسنده , , A. and Arulraj، نويسنده , , A. and Sundar، نويسنده , , C.S.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2012
  • Pages
    6
  • From page
    941
  • To page
    946
  • Abstract
    Magnetic properties of hole doped, oxygen deficient double perovskite compounds, Gd1 − xCaxBaCo2O5.5, have been investigated. Ferromagnetic transition temperatures increase and the anti-ferromagnetic transition temperatures decrease with Ca substitution leading to stabilisation of ferromagnetisim for x ≥ 0.05. A detailed study of the ferromagnetic phase indicates the presence of double hysterisis loops for Ca fractions, 0.05 ≤ x ≤ 0.2 in the 50–200 K temperature range, suggestive of the co-existence of two ferromagnetic phases with different co-ercivities. Based on the magnetisation and transport measurements a phase diagram is proposed for Ca doped GdBaCo2O5.5.
  • Keywords
    B. Chemical synthesis , D. Magnetic properties , A. Oxides , A. Magnetic materials
  • Journal title
    Materials Research Bulletin
  • Serial Year
    2012
  • Journal title
    Materials Research Bulletin
  • Record number

    2101760