Title of article
Pt/TiO2 composite nanoparticles synthesized by electron beam irradiation for preferential CO oxidation
Author/Authors
Kageyama، نويسنده , , Satoru and Sugano، نويسنده , , Yoshitsune and Hamaguchi، نويسنده , , Yukihiro and Kugai، نويسنده , , Junichiro and Ohkubo، نويسنده , , Yuji and Seino، نويسنده , , Satoshi and Nakagawa، نويسنده , , Takashi and Ichikawa، نويسنده , , Satoshi and Yamamoto، نويسنده , , Takao A. Yamamoto ، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
1347
To page
1351
Abstract
This paper describes a novel synthesis method of stabilizer-free Pt/TiO2 composite nanoparticles using electron beam irradiation. The chemical compositions were analyzed by inductively coupled plasma-atomic emission spectroscopy. The microstructures of the samples were observed by using transmission electron microscope. Pt nanoparticles with the sizes of 2–4 nm were deposited on TiO2 without any use of stabilizers. The concentrations of Pt ions and 2-propanol notably affected the size and shape of Pt nanoparticles. Their reactions of preferential CO oxidation were measured in temperature region from 60 to 140 °C. The Pt/TiO2 catalyst with spherical Pt nanoparticles exhibited a 67% of CO conversion rate and 100% of selectivity at a low temperature of 60 °C.
Keywords
D. Catalytic properties , C. Electron microscopy , A. Composites
Journal title
Materials Research Bulletin
Serial Year
2013
Journal title
Materials Research Bulletin
Record number
2103379
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