Author/Authors :
Xiong، نويسنده , , Rui and Tian، نويسنده , , Mingliang and Liu، نويسنده , , Hailin and Tang، نويسنده , , Wufeng and Jing، نويسنده , , Mingqiao and Sun، نويسنده , , Jiebing and Kou، نويسنده , , Qinhong and Tian، نويسنده , , Decheng and Shi، نويسنده , , Jing، نويسنده ,
Abstract :
Large size and high quality single crystals of quasi-two-dimensional thallium molybdenum purple bronze TlMo6O17 have been grown by electrolytic reduction of molten salt of Tl2CO3MoO3. The crystal structure is trigonal with space group P3̄m1 determined by X-ray diffraction and four-circle single crystal diffraction. The lattice parameters of the unit cell are: a=b=5.5282 Å, and c=13.6991 Å. The temperature dependence of resistivity and magnetic susceptibility confirmed that a metal-to-metal transition occurs near 110 K.
