Surface modification of carbon/epoxy prepreg using oxygen plasma and its effect on the delamination resistance behavior of carbon/epoxy composites

It was shown in previous study that the fracture toughness of carbon/epoxy laminated composites could be significantly improved by modifying the surface of the prepreg using Ar+ irradiation in an oxygen environment. In this study, the surface of carbon/epoxy prepreg was modified using an oxygen plasma to improve the delamination resistance behavior of carbon/epoxy laminated composites. The variation of the contact angle on the prepreg surface was determined as a function of the modification time, in order to determine the optimal modification time. An XPS analysis was conducted to investigate the chemical changes on the surface of the prepreg caused by the plasma modification. Mode I delamination resistance curves of the composites with and without surface modification were plotted as a function of the delamination increment. The results showed that the contact angle varied from ∼64° to ∼47° depending on the modification time and reached a minimum for a modification time of 30 min. The XPS analysis showed that the hydrophilic carbonyl CO group was formed by the oxygen plasma modification. The results also showed that the delamination resistance behavior was significantly improved by the plasma modification of the prepreg. This improvement was caused by the better layer-to-layer adhesion as well as increased interfacial strength between the fibers and matrix.