Microstructure and mechanical properties of CoCrFeNiTiAlx high-entropy alloys

CoCrFeNiTiAlx (x values in molar ratio, x = 0, 0.5, 1.0, 1.5 and 2.0) high-entropy alloys were prepared using a vacuum arc melting method. The effects of Al addition on microstructure and mechanical properties were investigated. The results show that only a face-centered cubic (FCC) crystal structure phase is observed in the CoCrFeNiTi alloy. The phase composition transforms to stabilized body-centered cubic (BCC) structure phases and typically cast dendrite structure appears when Al is added. The dendrite region is rich in Co, Ni, Ti and Al elements while the interdendrite region is rich in Fe and Cr elements. Subgrains and nanosized precipitates are observed in the as-cast CoCrFeNiTiAl alloy. These CoCrFeNiTiAlx high-entropy alloys exhibit excellent room-temperature mechanical properties. For CoCrFeNiTiAl1.0 alloy, the compressive strength and elastic modulus reach as high as 2.28 GPa and 147.6 GPa, respectively. High density of dimple-like structure is observed from the fracture surfaces of the Al0 alloy, while alloys with Al addition show typical cleavage fractures with river-like patterns and cleavage steps.