Author/Authors :
Alemi، Abdolali نويسنده Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran , , Khademinia، Shahin نويسنده Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran , , Sertkol، Murat نويسنده Department of Physics Engineering, Istanbul Technical University, Maslak, 34469, TR ,
Abstract :
در اين مقاله نانوپودر ليتيم دي سيليكات با روش هيدروترمال در دماي 180 درجه سانتي گراد و زمان هاي 48 و 72 ساعت سنتز شدند. براي اين كار از پيش ماده هاي Li2CO3 و SiO2.H2O با نسبت هاي مولي غيراستيوكيومتري 1:2(Li:Si) در محيط قليايي استفاده شد. محصول به دست آمده بوسيله ي روش هاي مختلف مانند طيف بيني هاي مادون قرمز FT-IR ، پراش اشعه ايكس (XRD) ، ميكروسكوپي الكتروني روبشي (SEM) و طيف‌سنج نوري (UV-Vis-NIR Spectroscopy) شناسايي شد. نتايج به دست آمده نشان داد كه محصول داراي شيكه بلوري مونوكلينيك بوده و جدب مناسبي در ناحيه UV دارد.
Abstract :
Lithium disilicate nano-powders were synthesized via a mild
condition hydrothermal reaction at 180 ?C for 48 and 72 h with a
non stoichiometric1:2 Li:Si molar ratio in NaOH aqueous solution
using Li2CO3 and SiO2.H2O as raw materials. The synthesized
materials were characterized by powder X-ray diffraction (PXRD)
technique and Fourier transform infrared (FTIR) spectroscopy.
The XRD data showed that the obtained materials crystallized in a
monoclinic crystal structure with a space group of Ccc2. The
morphologies of the synthesized nanomaterials were studied by
field emission scanning electron microscope (FESEM).
Ultraviolet–visible spectra showed that the nanostructured lithium
disilicate powders had good light absorption properties in the
ultraviolet light region. Photo luminescence spectra of the obtained
materials were investigated in an excitation wavelength of 281 nm.
Cell parameter refinement data of the obtained materials showed
that with increasing the reaction time, parameters a and b were
increased. So there is an expansion in the unit cell.
