Title of article
An in situ X-ray spectroscopic study of Mo6+ speciation in supercritical aqueous solutions
Author/Authors
Yan، نويسنده , , Hao and Mayanovic، نويسنده , , Robert A. and Anderson، نويسنده , , Alan J. and Meredith، نويسنده , , Peter R.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
3
From page
207
To page
209
Abstract
In situ XRF and Mo K-edge XAS measurements were made on the ID20-B beam line at the APS on MoO3 in 1 M H2O2 aqueous solution, at temperatures between 400 and 600 °C. The samples were analyzed using a modified Bassett-type hydrothermal diamond anvil cell. Our XRF measurements show that MoO3 is highly soluble in the supercritical H2O2 aqueous fluid. Analysis of XAS spectra shows that the Mo6+ ion exhibits consistent speciation in the H2O2 aqueous solution at temperatures ranging from 400 to 600 °C.
Keywords
XAS , XRF , Supercritical aqueous solutions , HDAC
Journal title
Nuclear Instruments and Methods in Physics Research Section A
Serial Year
2011
Journal title
Nuclear Instruments and Methods in Physics Research Section A
Record number
2208808
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