Influence of pore water chemistry on the swelling behavior of compacted clays

The influences of the exchange complex and pH of the solution used for cation saturation on Atterberg limits, compaction, and swelling potential of a compacted clay were investigated. The study involved transforming the exchange complex from a heterogeneous to a homogeneous one so that a frame of reference can be set for the clay behavior under such an ideal condition. The employed method for altering the exchange complex successfully yielded homo-ionic clay. The introduction of different species of cations gave rise to different particles associations. When introduced to the tested clay, potassium cations bond its particles with a rather strong bond (K-linkage), causing a drastic decrease in the specific area of the clay (about one-fourth of its untreated specific area), a decrease in the CEC, as well as a drastic decrease in the swell potential. For example, the swell pressure decreased from 1.87 kg/cm2 for the untreated samples to 0.4 kg/cm2 for the K-treated samples (under the same conditions). Also, the swell potential vs. time relationships can be modeled accurately using a rectangular hyperbola.