Leaching experiments on a Mn-rich slag from the recycling of alkaline batteries – Solid phase characterization and geochemical modeling

Square sections of a Mn-rich slag from an alkaline battery recycling plant were submitted to 6-month batch leaching procedures. High-Purity Water (HPW), acidic (pH 4) and alkaline (pH 12) conditions were used in order to observe the behavior of primary solid phases as well as the constituent elements (Mn, Mg, Al, Si, Ca). The experiments were coupled with both KINDIS(P) modeling and mineralogical study (SEM-EDS). Experimental results showed that the Mn-rich slag was sensitive to acidic conditions which induced the dissolution of primary phases. Moreover, pH 4 conditions did not result in the formation of newly formed solid products, leading to the greatest mobilization of metallic elements (especially Mn). Alkaline conditions favored the precipitation of secondary phases, especially rhodochrosite, calcite and Mg-saponite, inducing low mobilization of the contained elements. The KINDIS(P) modeling allowed the stability of primary phases and newly formed products to be predicted. Although the modeled results have to be considered with caution, they allow the assessment and understanding of future environmental behavior of the solid material in given conditions. In this case, the reuse of Mn-rich slag in acidic conditions has to be avoided because of the acidic dissolution of the primary phases.