PCB contamination from sampling equipment and packaging

Work reported in this paper suggests that there are cases of contamination of soil and water samples by polychlorinated biphenyls (PCB) from paper and plastic packaging. Soil samples, which have been stored in paper bags for more than 20 years, share a similar congener distribution as the bags. Analyses showed a predominance of light congeners. PCB-analyses of water also indicate that water samples could be contaminated by plastic packaging. All analytical results of solid material packaging, as well as soil stored in the packaging, show a high relative amount of light weight PCB congeners. The paper bags that were analysed are made of strong paper and very popular among geochemists because of their watertight quality. These paper bags were manufactured more than 20 years ago. The plastic packaging that was analysed was produced in 1997 and 2008. The analyses of plastic and paper show that the raw material that has been used in the production at different times contains a wide concentration range of PCB. Re-sealable plastic bags, which contained the highest levels of PCB of the plastic material, are used by researchers world-wide as sampling bags for soils and sediments. This paper raises an important issue that packaging may potentially contaminate the samples that they hold.