Author/Authors :
Kong، نويسنده , , Shaofei and Lu، نويسنده , , Xiao-Bing and Bai، نويسنده , , ZhiPeng and Zhao، نويسنده , , Xueyan and Chen، نويسنده , , Li and Han، نويسنده , , Bin and Li، نويسنده , , Zhiyong and Ji، نويسنده , , Yaqin and Xu، نويسنده , , Yonghai and Liu، نويسنده , , Yong and Jiang، نويسنده , , Hua، نويسنده ,
Abstract :
30 re-suspended dust samples were collected from building surfaces of an oilfield city, then re-suspended through PM2.5, PM10 and PM100 inlets and analyzed for 10 metals including V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd and Pb by inductively coupled plasma-mass spectroscopy. Metals concentrations in different fractions and locations were studied. Metals sources were identified by cluster and primary component analysis. The potential risk to human health was assessed by human exposure model. Results showed that Zn, Mn, Pb and Cu were higher in all the three fractions. V, Cr, Mn and Co ranged close to the background values of Chinese soil indicating that they were mainly from crustal materials. Concentrations of Zn, Mn, Pb, V, Cr, Ni, Co and Cd were higher in old district than that in new district for the three fractions. The PM2.5/PM10, PM10/PM100 and PM2.5/PM100 ratios were higher for Zn, Cd, Cu, Pb, Ni, As and Cr (all higher than 1.0), and lower for Co, Mn and V (all less than or close to 1.0) which meant that anthropologic sources associated metals were more easily accumulated in finer particles than metals from crustal materials. Spatial variations indicated that the ten metals peaked at surroundings near railway station, gas stations, industrial boilers and machine manufacturing plant implying the influence of local vehicle emission, fossil fuel combustion and industrial activities as well as crustal materials which was verified by cluster analysis and primary component analysis results. Ingestion of dust particles appeared to be the main route of exposure to re-suspended dust. Hazard Indexes of As were both highest for children and adult which could be a potential threat to human health for non-cancer effect and it also exhibited the highest values for cancer effect as 1.01E-06, 7.04E-07 and 7.21E-07 for PM2.5, PM10 and PM100, respectively.
Keywords :
Re-suspended dust , Dongying , Health risk , Oilfield city , sources , Heavy metals