The evolution from Miocene potassic to Quaternary sodic magmatism in western Turkey: implications for enrichment processes in the lithospheric mantle

New K-Ar dating and major- and trace-element analyses from the Uşak-Selendi-Emet (USE) area constrain the timing of changes in the nature of volcanism in the Miocene in western Turkey. The data reveal a change from dominantly calc-alkaline and silicic in the Early Miocene to largely alkaline and more mafic volcanism in the Middle Miocene. This probably reflects a decreasing amount of crustal contamination with time, a result of extensional tectonics. High levels of various incompatible elements (including K) in the more mafic members, suggest an enriched subcontinental lithospheric source region for the Middle Miocene USE lavas. Highly variable NbY, TiY and ThNb ratios suggest a lithospheric mantle heterogeneously enriched by two processes: (1) enrichment by subduction-related processes producing high ThNb but low NbY and TiY; and (2) enrichment by small degree melts of depleted upper mantle producing low ThNb but high NbY and TiY. Both of these enrichment processes have variably contributed to Middle Miocene K-rich lavas in the USE area. The mechanism which initiated the melting of the enriched lithosphere is considered to be extension which produced decompression melting. Comparisons with the nearby Kula lavas reveals that by the Pliocene to Quaternary, volcanism, although still enriched in incompatible elements, had become sodic. It seems likely that continued extension up to this time thinned the lithosphere to such an extent that asthenospheric melts were produced which ascended and mixed with previously enriched lithosphere.