Records of climatic changes in the carbonate profiles of Russian Chernozems

The carbonate profiles of Chernozems bear important information on soil processes and can be successfully used for paleoenvironmental reconstruction. In the Northern Caucasus region, Russia, carbonate profiles of Chernozems were compared under anthropogenic (irrigation) and natural changes of moisture regime. The results for irrigation served as the basis for understanding the response to natural climatic changes. A soil chronosequence, consisting of soils buried under archaeological mounds dated to >5000, 3800–4000 and 1600–1700 BP and modern surface soils, was studied in a similar way. The soils buried >5000 and 3800–4000 BP had distinctive migrational and segregational carbonate accumulations (CAs). The migrational forms occurred in the surface horizons and contained 89–92% calcite with the highest dissociation temperatures. In the soils buried 1600–1700 BP the carbonate profile was clearly defined in terms of migrational CAs; they occurred only in the deeper horizons, had no clear boundaries and were diffused throughout the soil mass. In the modern surface soils the migrational CAs have almost disappeared, and the segregational CAs have the largest halos of recrystallised carbonates. The values of δ13C for CAs in the soils buried >5000 and 3800–4000 BP were lighter than in the soils buried 1600–1700 BP and the modern surface soils (−10.6‰ to −9.9‰ and −9.6‰ to −8.8‰, respectively). We conclude that the climate of the region during the second half of the Holocene changed from relatively dry and warm in the Atlantic period (>5000 BP) to more humid and cooler in the early Subboreal (5000–4000 BP). Since 4000 BP the climatic conditions have remained relatively stable with some changes in moisture regime resulting from human activities in recent centuries.