Petrologic evidence for K-feldspar metasomatism in granulite facies rocks

We present evidence for K-feldspar metasomatism in charnockitic granulites from two well-known terranes: the Shevaroy Hills Massif, S. India (750°C, 8 kbars) and the Bamble Sector, S.E. Norway (790°C, 7.5 kbars) in the form of K-feldspar veins principally along plagioclase and quartz grain boundaries and in the form of highly variable antiperthitic patches of K-feldspar in an uneven scattering of plagioclase grains. With one exception, orthopyroxene or amphibole grains in contact with these K-feldspar veins show no alteration to secondary biotite, indicating that the H2O activity of the fluids responsible for these veins must have been relatively low. A high Ba concentration in these veins also suggests a metasomatic origin. Point counted, back-scattered electron photomicrographs, along with microprobe analyses, provide reintegrated K-feldspar and plagioclase compositions for 8 to 12 predetermined random areas per thin section for three samples from Bamble and three samples from the Shevaroy Hills. These reintegrated feldspar compositions plot over a range of temperatures on the feldspar ternary for each sample, and indicate saturation temperatures above the mean temperature for either region with a few reintegrated compositions above the 1000°C isotherm and with the lower cut-off temperatures at 700°C and 600°C for the Shevaroy and Bamble samples, respectively. These patterns suggest that exsolution alone could not have been responsible for the formation of the K-feldspar veins and patches in these rocks. We suggest that these veins are due to the influx of complex, supercritical, low H2O activity brines shortly after peak metamorphic conditions, that this influx continued during the initial phases of post-peak metamorphic uplift and that these fluids represent the first stage in a series of fluid influxes in which the H2O activity increased as uplift continued. Reaction of these brines with potassium-undersaturated plagioclase grains formed K-feldspar veins along grain boundaries and fractures, as well as diffusing into the plagioclase, which became supersaturated, and exsolved K-feldspar as antiperthite patches during uplift and cooling. Formation of secondary biotite halos around orthopyroxene in one sample associated with these K-feldspar veins can be explained by heightened H2O activity in the brines due to enrichment in H2O, emplacement of the veins at lower pressure during uplift or both compared to the other Shevaroy and Bamble samples.