Ignition of ethanol-containing mixtures excited by nanosecond discharge above self-ignition threshold

The kinetics of ignition in lean and stoichiometric C2H5OH:O2:Ar mixtures by a high-voltage nanosecond discharge are studied experimentally and numerically for gas temperatures above self-ignition threshold. Autoignition delay time and ignition delay after a high-voltage nanosecond impulse discharge are measured using reflected shock-wave technique. It is shown that the additional excitation by the discharge plasma leads to an order of magnitude decrease in ignition delay. Discharge processes are simulated on the basis of the measured time–resolved discharge characteristics. The densities of atoms, radicals and excited and charged particles produced in the discharge phase are calculated and used as initial conditions for chemical modeling. Calculated ignition delay times agree well with measurements with and without the discharge plasma. Calculations show that the effect of the discharge plasma on ignition of the ethanol-containing mixtures is primarily associated with active species production in the discharge phase; the role of fast gas heating during the discharge and in its afterglow is relatively small. A method is suggested to compare the effect of nonequilibrium pulse discharge plasma on ignition in different fuel–air and fuel-oxygen mixtures above self-ignition temperatures. It is shown that this effect is more profound at low gas temperatures when the thermal production of initial radicals is not efficient. Due to O2 dissociation in the discharge phase, the influence of nonequilibrium discharge plasma on ignition is more pronounced for fuels with high activation energy of thermal dissociation (like H2 and CH4). The role of N2 in favoring plasma-assisted ignition owing to additional O2 and fuel dissociation is demonstrated.