Tracing and dating recent chemical transfers in weathering profiles by trace-element geochemistry and 238U234U230Th disequilibria: the example of the Kaya lateritic toposequence (Burkina-Faso)

The paper presents a synthesis of the approach recently developed to constrain the nature and the age of recent element mobility in weathering profiles. The approach relies on a comparison of variations of trace elements and U-series disequilibria in weathering profiles. It is exemplified in the case of old lateritic profiles from the Kaya toposequence, Burkina Faso. Trace elements and 238U234U230Th disequilibria have been analysed in whole rock samples from two pits located in very contrasted topographical positions. Trace element data show that the whole toposequence is marked by an intense chemical remobilization, including uranium, from the cap to the lower part of the profiles. 238U234U230Th disequilibrium data outline that all the levels of the profiles are affected by recent UTh fractionations, and that each level of the toposequence is marked by U gains and losses. The chronological approach developed in this paper leads to an age of about 400 kyr for the dismantling of the iron cap, and ages ranging from 0 to 400 kyr for U accumulation in the pink clay horizon of the profiles. The depth repartition of U accumulation in the profile implies that the remobilisation processes in this toposequence varied through time, on time constants similar to those of climatic variations. To cite this article: F. Chabaux et al., C. R. Geoscience 335 (2003).