Title of article
Stability of chiral states, role of intermolecular interactions and molecular parity violation
Author/Authors
Bahrami، نويسنده , , Mohammad and Shafiee، نويسنده , , Afshin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
84
To page
87
Abstract
We study the problem of stability of chiral states, also known as problem of chirality, within the framework of a two-dimensional approximation of a symmetric double-well potential. We show how the symmetry breaking of the potential due to the molecular parity violation can stop the tunneling in a coherent way, accordingly stabilize the chiral states. Then, we use the quantum Brownian motion within a linear Lindblad-type equation to model how the intermolecular interactions make the tunneling incoherent, thus inducing a racemization by dephasing. Finally, we investigate the normal physical conditions where the dephasing racemization does not suppress the effects of the molecular parity violation, accordingly the molecular parity violation may be observed experimentally.
Keywords
Optical activity , Chirality , Decoherence , Molecular parity violation , Hund paradox
Journal title
Computational and Theoretical Chemistry
Serial Year
2011
Journal title
Computational and Theoretical Chemistry
Record number
2285240
Link To Document