• Title of article

    Stability of chiral states, role of intermolecular interactions and molecular parity violation

  • Author/Authors

    Bahrami، نويسنده , , Mohammad and Shafiee، نويسنده , , Afshin، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2011
  • Pages
    4
  • From page
    84
  • To page
    87
  • Abstract
    We study the problem of stability of chiral states, also known as problem of chirality, within the framework of a two-dimensional approximation of a symmetric double-well potential. We show how the symmetry breaking of the potential due to the molecular parity violation can stop the tunneling in a coherent way, accordingly stabilize the chiral states. Then, we use the quantum Brownian motion within a linear Lindblad-type equation to model how the intermolecular interactions make the tunneling incoherent, thus inducing a racemization by dephasing. Finally, we investigate the normal physical conditions where the dephasing racemization does not suppress the effects of the molecular parity violation, accordingly the molecular parity violation may be observed experimentally.
  • Keywords
    Optical activity , Chirality , Decoherence , Molecular parity violation , Hund paradox
  • Journal title
    Computational and Theoretical Chemistry
  • Serial Year
    2011
  • Journal title
    Computational and Theoretical Chemistry
  • Record number

    2285240