Depositional conditions and organic matter preservation pathways in an epicontinental environment: the Upper Jurassic Kashpir Oil Shales (Volga Basin, Russia)

The Middle Volgian Kashpir Oil Shales Formation, located on the Russian Platform, is a lateral equivalent of the North Sea and West Siberian petroleum source rocks. In the Volga Basin, this formation is 6 m thick and shows alternations of marls and black shales. The organic carbon content is often higher than 1%, although bioturbation and benthos are abundant, even in the black shales. In the marls, highly degraded organic matter (OM) dominates, while aliphatic, sulphur-rich OM is dominant in the black shales. The combination of sedimentological and geochemical studies allowed to determine that the redox conditions of the sediment regularly fluctuated from oxic to anoxic, under relatively productive waters, while climatic conditions were increasingly arid. It is proposed that OM deposition occurred in relation to the increasing aridity, through the combination of recurrent disruption of salinity stratification and aeolian supply of iron, which both promoted phytoplankton productivity.