Clay mineralogy of the middle Mingshui Formation (upper Campanian to lower Maastrichtian) from the SKIn borehole in the Songliao Basin, NE China: Implications for palaeoclimate and provenance

Clay mineralogy of a 60 m thick section of the middle Mingshui Formation (upper Campanian to lower Maastrichtian) from the SKIn borehole (Songliao Basin in NE China) has been studied to assess the palaeoclimate and provenance. The sedimentary succession is composed of shore to shallow lacustrine mudstones and siltstones in the lower part, and meandering fluvial sandstone–mudstone sequences in the upper part. The clay mineral assemblage is characterized by the predominance of smectitic minerals, with some exceptions of illite-rich layers, and trace amounts of kaolinite and chlorite. The high smectite content (> 90% on average) in lacustrine sediments could source from erosion of smetitic soils and volcanic materials in source areas. The Lesser Xingʹan–Zhangguangcai Range was the potential provenance area for the sediments, with volcanic activity occurring at ~ 70 Ma, when the temperate semi-humid palaeoclimate was favorable for the clay formation. Smectite presented in meandering fluvial sandstones is of early diagenetic origin, formed by hydrolysis and alteration of primary minerals after deposition. Illite in overbank deposits is interpreted as a result of erosion of granitic rocks and sorting in sedimentation processes. The clay mineralogy of the studied strata contains information on palaeoclimate and provenance, although early diagenetic processes may have influenced the mineralogical composition in some intervals of sandstones.