Tritium recovery from lithium, based on a cold trap

A concept to recover tritium from lithium, based on a cold trap, has been developed as part of the U.S. contribution to ITER. The cold trap process can only reduce the tritium concentration to about 400 appm, which is far above the ITER design goal of reducing the tritium concentration in lithium to about 1 appm. To achieve this lower goal, protium is added to the lithium to a concentration higher than the saturation concentration of the hydrogen isotope at the cold trap temperature. Thus, LiH and LiT will precipitate out together at the cold trap. The tritium from the cold trap can be recovered by heating the Li(H + T) to 600 °C for decomposition. The H and T then can be separated by a cryogenic distillation process.